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Editor:ESTL Category:Technical information Release time:2026-06-05 Click volume:5
In global international trade, all goods containing lithium batteries—whether shipped standalone or pre-installed inside finished equipment—almost always require two core documents by freight forwarders and airlines: UN38.3 test report (together with test summary) plus SDS (formerly named MSDS, Material Safety Data Sheet). Many exporters regard SDS as a routine procedural document only; in fact, it is a legally binding technical file whose compilation quality directly decides customs clearance efficiency. Based on practical lithium battery shipping scenarios, this article systematically elaborates SDS composition, drafting specifications and application procedures for lithium cells & packs.
SDS (Safety Data Sheet, previously MSDS under legacy naming) is a standardized technical document detailing chemical composition, hazard classification, storage & transportation rules and emergency response measures for lithium cells and packs under the global GHS regulation framework.
Compared with conventional chemical substance SDS, lithium battery SDS features four unique characteristics:
表格
| Section No. | Section Title | Core Content for Lithium Battery |
|---|---|---|
| 1 | Product & Supplier Identification | Battery name (Lithium-ion cell / battery pack), intended usage, manufacturer info, 24h emergency contact |
| 2 | Hazard Identification | GHS classification (usually Class 9 Miscellaneous Dangerous Goods), signal word “WARNING”, hazard pictograms & precautionary statements e.g. risk of explosion under fire exposure |
| 3 | Composition / Ingredient Info | Cathode (NCM/LiFePO₄), graphite anode, LiPF₆ carbonate electrolyte plus corresponding CAS registry numbers |
| 4 | First-Aid Measures | Skin contact: soap & clean water rinse; eye splash: continuous fresh water flush for 15min; inhalation: move to open air; ingestion: immediate medical treatment |
| 5 | Fire-Fighting Instructions | Approved extinguishing agents: dry powder, CO₂, Class D fire extinguisher; prohibit water dousing; HF toxic gas may generate during battery combustion |
| 6 | Spill Control & Cleanup | Damaged batteries sealed inside metal containers; leaked electrolyte absorbed by inert media (vermiculite/sand); avoid sewage drain contamination |
| 7 | Handling & Storage | Prevent short-circuit, puncture & high temperature (storage below 60°C); store in dry ventilated warehouse away from combustibles & oxidants |
| 8 | Exposure Control & PPE | No special protective gear for intact battery handling; solvent-resistant gloves, goggles & protective clothing required for damaged unit disposal |
| 9 | Physical & Chemical Properties | Solid cell/pack appearance; no fixed boiling/melting point due to hermetic enclosure; electrolyte flash point: 23~35°C |
| 10 | Stability & Reactivity | Chemically stable under normal operation; avoid over 130°C, short-circuit, crushing and piercing; isolate from strong oxidizing agents |
| 11 | Toxicological Information | Sealed intact batteries non-toxic; leaking electrolyte irritates skin & respiratory tract; LiPF₆ hydrolyzes into highly corrosive HF upon water contact |
| 12 | Ecological Data | Forbid random discharge into water environment; electrolyte harmful to aquatic organisms; scrapped batteries subject to regulated professional recycling |
| 13 | Disposal Guidance | Full discharge before authorized recycler collection; never discard into domestic waste, comply with local waste battery environmental regulations |
| 14 | Transport Information | UN number, Class 9 hazard division, IATA PI965-PI970 packing instruction, proper shipping name referencing IATA DGR 63rd |
| 15 | Regulatory Information | GB/T 16483-2008 (China SDS standard), EU REACH (EC) No 1907/2006, US TSCA compliance clauses |
| 16 | Other Information | SDS issue date, revision log, disclaimer and attached valid UN38.3 test report reference number |
Lead Time: 1~3 working days with available UN38.3 report; total 3~5 weeks if UN38.3 testing needs to be scheduled together.
UN38.3 and SDS form an indispensable dual-file set for lithium battery export rather than interchangeable documents:
In real logistics practice, airlines and ocean carriers commonly demand UN38.3 test summary + SDS simultaneously; multiple forwarders additionally require third-party dangerous goods appraisal certificate to confirm hazard category and applicable packing specs.
Fact: IATA DGR Clause 4.1.6 and IMDG Code 5.4.4 legally oblige shippers to provide compliant safety data documentation; GHS has been enforced compulsorily across 71 global jurisdictions.
Fact: Different cathode formulas and Wh ratings change hazard & transport rules (e.g. above/below 20Wh cells adopt varied IATA packing standards); separate SDS required per distinct part number.
Fact: SDS expires upon underlying data update: battery material reformulation, over 10% capacity alteration, UN38.3 report expiry or official GHS version upgrade (e.g. Rev.7 updated to Rev.8) all trigger mandatory SDS revision.
Fact: EU, USA, Japan and most international customs require English or local-language SDS; bilingual Chinese & English edition is strongly recommended for global shipments.
Fact: While blank GHS templates are publicly available, professional hazard classification (Section2) and dangerous goods transport judgment (Section14) need certified technical evaluation; third-party CNAS/CMA lab-stamped SDS gains universal recognition by carriers and customs authorities.
SDS is an irreplaceable compliance document for worldwide lithium battery trading. It translates complex electrochemical safety parameters into standardized risk control language acceptable for shipping companies and customs. Three core rules for qualified SDS: compiled upon valid UN38.3 test data, drafted per latest GHS Rev.8 specifications, officially sealed English version released by accredited third-party labs.
Contact us for professionally compiled transport-compliant lithium battery SDS.
Disclaimer: This content is AI-assisted for reference only, not legally binding certification advice. All implementation shall abide by the latest released official global regulatory provisions.
Label: lithium battery customs clearance document UN38.3 & SDS for air shipping GHS Rev.8 safety data sheet Lithium battery SDS MSDS IATA DGR PI965-PI970
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